A likely possibility is that homoglutathione replaces glutathione as the dominant cellular redox-buffer in tissues associated with nitrogen fixation, as homoglutathione is required for proper development of nodules (Frendo et al., For biosynthesis of glutathione and homoglutathione share a common first reaction, i.e., the synthesis of -glutamylcysteine, but the chemical diversity results from altered specificity for the nucleophilic amino acid in the second reaction of the pathway
Lean too long on the renewal side, always restricting, and you lose the tissue you are trying to keep
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Legault Z, Bagnall N, Kimmerly DS